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Storing Sulfuric Acid in Poly
Tanks |
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HDPE Polyethyelene is a good material
for sulfuric acid storage tanks. It is good, but just like
with steel tanks, HDPE is not perfect.
Sulfuric acid in
high concentrations will attack just about any material.
That means the tanks should be monitored and replaced when
needed. |
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Exxon Chemical did a comparative study
and found that HDPE (sometimes incorrectly referred to as
HDLPE) is better at
resisting the chemical attack of highly concentrated sulfuric
acid than XLPE. XLPE is also known as crosslinked
polyethylene. Exxon Chemical is one of the largest
producers in the world of both HDPE and XLPE. |
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One of the concerns with storing
concentrated Sulfuric Acid in any tank is the heat that is given
off when any water comes in contact with the acid. Under
no circumstances should a plastic tank be used as a mixing tank
for concentrated sulfuric acid and water. The heat that
results from the exothermic reaction can raise the temperature
above the safe operating temperature of the tank and cause tank
failure. Poly tanks should only be used for bulk storage
of sulfuric acid. |
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We recommend the use of a heavy wall
tank for the storage of concentrated sulfuric acid. We
recommend the use of
a tank rated to 2.2 specific gravity.
That is a tank rated for liquids 2.2 times the weight of water.
Concentrated sulfuric acid has a specific gravity of over 1.8
and we recommend taking extra precautions when storing it. |
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Any water that enters the tank through
the vent such as humidity that condenses inside the tank will
cause heat to be given off when it comes in contact with the
acid. Since sulfuric acid is so dense, water that enters
the tank but is not mixed will dilute only the top layer of
acid. That will cause heat to be given off along an narrow
band along the tank wall. |
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